刘恩辉导师主页
基本信息
姓名: 刘恩辉
职称: 教授
单位电话: 07328292202
电子信箱: liuenhui99@sina.com
办公室: 应用化学教研室
个人主页:
http://202.197.224.66:8084/gmis/default.aspx
个人简介

刘恩辉,博士,教授,博士生导师。《大学化学基础》国家级精品课程主持人,Electrochem.Commun.,Electrochim. Acta, Mater. Chem. Phys., Mater. Lett.等刊物审稿人,国家及湖南省自然科学基金通讯评议专家,湖南省科技奖励会评专家,湖南、内蒙等省科技奖励通讯评议专家。主要研究方向为电化学理论与技术、电化学电极活性材料的制备、结构表征与性能研究以及超级电器、锂离子电池、镍氢电池等先进化学电源的研发技术。近年来发表通讯作者SCI 学术研究论文30余篇, “A doped activatedcarbon prepared from polyaniline for high performance supercapacitors. J. PowerSources 195 (2010):1516.”ESI(基本科学指标)研究论文。获中国授权发明专利1 项;获得2012 年度湖南省自然科学二等奖(2完成人);主持国家自然科学基金项目1项;主持湖南省自然科学基金项目2(其中1 项为重点项目);指导教育部大学生研究性学习和创新性实验计划项目2项。主讲《大学化学基础》、《无机化学》、《普通化学》、《膜分离技术及应用》、《电极材料》、《无机化学实验》、《综合化学实验》等本科生课程,主讲《理论电化学》、《新能源材料》等研究生课程。

研究方向

1. 电化学储能装置,包括锂离子电池、镍氢电池、新型二次碱性电池、超级电容器、超级电容电池等。

2. 先进功能材料,包括电化学电极活性材料、先进炭材料等。

3. 复杂工业废弃物、废旧化学电源的资源化、无害化处理等。

4. 电化学表面处理。



科研项目

1. 国家自然科学基金项目:含氮纳米层次结构碳材料的可控制备及其超级电容器储能机理(51172190),60万元。

2. 湖南省自然科学基金重点项目:含氮纳米层次结构碳的可控制备及其超级电容器储能机理(11JJ2030),10万元。



主要代表性论文

[1] Limin Li, Enhui Liu*, Jian Li, Yanjing Yang, Haijie Shen, Zhengzheng Huang, Xiaoxia Xiang, WenLi. A doped activated carbon prepared from polyaniline for high performancesupercapacitors. J. Power Sources195 (2010):1516-1521. (ESI研究论文)

[2] Yuan Teng, Enhui Liu*,Rui Ding, Kun Liu, Ruihua Liu, Luo Wang, Zeng Yang, Haixia Jiang. Beandregs-based activated carbon/copper ion supercapacitors. Electrochimica Acta194 (2016):394–404.

[3] Tiantian Liu, Enhui Liu*,Rui Ding, Zhenyu Luo, Tiantian Hu, Zengpeng Li. Preparation and supercapacitiveperformance of clew-like porous nanocarbons derived from sucrose by catalyticgraphitization. Electrochimica Acta 173 (2015):50-58.

[4] Tiantian Liu, Enhui Liu*, Rui Ding, Zhenyu Luo, Tiantian Hu, and Zengpeng Li. Highly GraphiticClew-Like Nanocarbons for Supercapacitors. ChemElectroChem 2(2015):852-858.

[5] Longchu Song, Yunlong Yang, Haibo Xie, Enhui Liu*. Cellulose Dissolution and In Situ Grafting in aReversible System using an Organocatalyst and Carbon Dioxide. ChemSusChem 8(2015):3217-3221.

[6] YinhaiZhu, Enhui Liu*, Zhenyu Luo,Tiantian Hu, Tiantian Liu, Zengpeng Li, Qingling Zhao. A hydroquinone redoxelectrolyte for polyaniline/SnO2supercapacitors. Electrochimica Acta 118 (2014):106-111.

[7] Xiaoxia Xiang,Zhengzheng Huang, Enhui Liu*, Haijie Shen, YingyingTian, Hui Xie, Yuhu Wu, Zhilian Wu. Lithiumstorage performance of carbon nanotubes prepared from polyaniline forlithium-ion batteries. ElectrochimicaActa 56(2011):9350-9356.

[8] Yunlong Yang, Haibo Xie, Enhui Liu*. Acylation of cellulose inreversible ionic liquids. Green Chem.16(2014):3018-3023.

[9] Zhilian Wu, Haibo Xie, Xue Yu, EnhuiLiu*. Lignin-Based Green Catalyst for the Chemical Fixation of CarbonDioxide with Epoxides To Form Cyclic Carbonates under Solvent-Free Conditions. ChemCatChem 5(2013):1328-1333.

[10] RuihuaLiu, EnhuiLiu*, RuiDing,KunLiu, YuanTeng, ZhenyuLuo, ZengpengLi, TiantianHu, Tiantian Liu. Facile in-situ redoxsynthesisofhierarchicalporousactivatedcarbon@MnO2 core/shellnanocompositeforsupercapacitors. Ceramics International 41(2015):12734–12741.

[11] Tian-tianLIU, Yin-hai ZHU, En-hui LIU*,Zhen-yu LUO, Tian-tian HU, Zeng-peng LI, Rui DING. Fe3+/Fe2+ redox electrolytefor high-performance polyaniline/SnO2 supercapacitors. Trans. Nonferrous Met.Soc.China25(2015):2661?2665.

[12] Zhenyu Luo, EnhuiLiu*, Tiantian Hu, Zengpeng Li, TiantianLiu. Effect of synthetic methods on electrochemical performances of VOPO4·2H2Osupercapacitor. Ionics 21 (2015):289-294.

[13] Enhui Liu*Haijie ShenXiaoxia XiangZhengzhengHuangYingying TianYuhu WuZhilian WuHuiXie. A novel activated nitrogen-containing carbon anode material for lithiumsecondary batteries. Materials Letters67(2012):390-393.

[14] Zhengzheng Huang, Enhui Liu*, Haijie Shen,Xiaoxia Xiang, Yingying Tian, Chengyi Xiao, Zhaohui Mao. Preparation ofpolyaniline nanotubes by a template-free self-assembly method. Materials Letters 65(2011):2015-2018.

[15] Limin Li, Enhui Liu*, Yanjing Yang, Haijie Shen, Zhengzheng Huang, Xiaoxia Xiang.Nitrogen-containing carbons prepared from polyaniline as anode materials forlithium secondary batteries. MaterialsLetters 64 (2010):2115-2117.

[16] Yan-jing Yang, En-hui Liu*, Li-min Li, Zheng-zheng Huang, Hai-jie Shen, Xiao-xia Xiang.Nanostructuredamorphous MnO2 prepared by reaction of KMnO4 withtriethanolamine. J. Alloys and Compounds505 (2010):555-559.

[17] X. Xiang, E.  Liu*, Y.Wu, Y. Tian, H. Xie, Z.Wu, Y. Zhu. Nitrogen- and Oxygen-Enriched Carbon With Square Tubular StructurePrepared FromPolyaniline as Electrode for Supercapacitors. FUEL CELLS 12(2012):892-897.

[18] Zengpeng Li, Enhui Liu*, Yinhai Zhu, Tiantian Hu, Zhenyu Luo, Tiantian Liu.Enhanced supercapacitive performance of porous activated carbon derived frompolyaniline prepared by electrochemical synthesis. Materials Research Bulletin 64 (2015):6-11.

[19] ZhenyuLuo, Yinhai Zhu, Enhui Liu*,Tiantian Hu, Zengpeng Li, Tiantian Liu, Longchu Song. Synthesis ofpolyaniline/SnO2 nanocomposite and its improved electrochemicalperformance. Materials Research Bulletin60 (2014):105-110.

[20] Hui Xie, Yinhai Zhu, Yuhu Wu, Zhilian Wu, Enhui Liu*. The effect of hydroquinoneas an electrolyte additive on electrochemical performance of the polyanilinesupercapacitor. Materials Research Bulletin2014(50):303-306.

[21] Yinhai Zhu, Xiaoxia Xiang, Enhui Liu*, Yuhu Wu, Hui Xie, Zhilian Wu, Yingying Tian. An activated microporouscarbon prepared from phenol-melamine-formaldehyde resin for lithium ion batteryanode. Materials Research Bulletin47(2012):2045-2050.

[22] Haijie ShenEnhui Liu*XiaoxiaXiangZhengzheng HuangYingying TianYuhu WuZhilian WuHuiXie. A novel activated carbon for supercapacitors. Materials Research Bulletin 47(2012):662-666.

[23] Xiaoxia Xiang, Enhui Liu*, ZhengzhengHuang, Haijie Shen, Yingying Tian, Chengyi Xiao,Jingjing Yang, Zhaohui Mao.Microporous carbon derived from polyaniline base as anode material for lithiumion secondary battery. MaterialsResearch Bulletin46(2011):1266-1271.

[24] Xiaoxia XiangEnhui Liu*HuiXieYingying TianYuhu WuZhilian WuYinhai Zhu. Highly stable performance of supercapacitors using microporouscarbon    derived from phenol–melamine–formaldehyde resin. J Solid  State Electrochem16(2012):2661-2666.

[25] Xiaoxia Xiang, Enhui Liu*,Limin Li, Yanjing Yang , Haijie Shen, Zhengzheng Huang, Yingying Tian.Activated carbon prepared from polyaniline base by K2CO3 activationfor application in supercapacitor electrodes. J. Solid State Electrochem.15(2011):579-585.

[26] Xiaoxia Xiang, Enhui Liu*, ZhengzhengHuang, Haijie Shen, Yingying Tian, Chengyi Xiao,Jingjing Yang, Zhaohui Mao.Preparation of activated carbon from polyaniline by zinc chloride activation assupercapacitor electrodes. J. SolidState Electrochem.15(2011):2667-2675.

[27] Limin Li, Enhui Liu*, Haijie Shen,Yanjing Yang , Zhengzheng Huang, Xiaoxia Xiang, Yingying Tian. Charge storageperformance of doped carbons prepared   from polyaniline forsupercapacitors. J. Solid StateElectrochem.15(2011):175-182.

[28] Zhenyu Luo, Enhui Liu*, Tiantian Hu, Zengpeng Li, Tiantian Liu. Effect of synthetic methods onelectrochemical performancesof VOPO4·2H2O supercapacitor.Ionics 21 (2015):289-294.

[29] Yinhai Zhu, Xiaoxia Xiang, EnhuiLiu*, Yuhu Wu, Hui Xie,  Zhilian Wu,Yingying Tian. A microporous carbon derived from phenol–melamine–formaldehyderesin by K2CO3 activation for lithium ion batteries. Ionics 19(2013):409-414.



发明专利

刘恩辉, 李利民, 李剑, 向晓霞, 黄铮铮, 杨艳静, 沈海杰. 一种活性碳基材料及制备方法, 2012.9, 中国,ZL 2010 1 0123555.7.


成果获奖

具有光电磁功能的金属及氧化物/聚合物材料与器件研究,湖南省人民政府,湖南省自然科学奖,二等奖(排名第二),2012.

精品课程

1. 《大学化学基础》国家级精品课程课 负责人

2. 《大学化学基础》国家级精品资源共享课 负责人